International Journal of Applied Science and Engineering
Published by Chaoyang University of Technology

Maria Cristina Macawile1,2*, Joseph Auresenia1

1 Gokongwei College of Engineering, De LaSalle University 2401 Taft Avenue, Malate, Manila, 1004 Philippines

2 College of Engineering, Architecture, and Technology, De LaSalle University - Dasmariñas DBB-B, 4115 West Ave, Dasmariñas, Cavite, 4114, Philippines

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ABSTRACT

The seeds from Hibiscus cannabinus and Gliricidia sepium, also known as kenaf and kakawate seeds respectively, were used as sources of oil in the production of biodiesel. The oil was extracted using two methods: ultrasound-assisted chemical solvent (UACS) and supercritical fluid. The performances of two methods were compared based on their oil and biodiesel yields. Using supercritical CO2 (SCCO2), the highest oil yield recorded was 13.19% from kenaf at operating conditions of CO2 flow rate=2.5ml/min, T=70oC, P=30MPa, and 11.79% from kakawate at operating conditions of CO2 flow rate = 2.5ml/min, T=60oC, P=30 MPa. Using multi-walled carbon nanotubes and concentrated sulfuric acid under thermal decomposition, a sulfonic catalyst was produced and used in simultaneous esterification-transesterification reactions. The individual chemical compositions of kakawate and kenaf methyl esters were analyzed using gas chromatography–flame ionization detector. Higher biodiesel yields were observed for oil samples extracted using SCCO2.


Keywords: Biodiesel, Extraction, Kakawate, Kenaf, Supercritical carbon dioxide.


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REFERENCES

  1. Abdolshahi, A., Majd, M.H., Rad, J.S., Taheri, M., Shabani, A., da Silva, J.A. 2015. Choice of solvent extraction technique affects fatty acid composition of pistachio (Pistacia vera L.) oil. Journal of Food Science and Technology, 52, 2422–2427. https://doi.org/10.1007/s13197-013-1183-8

  2. Akinfalabi, S., Rashid, U., Yunus, R., Taufiq-Yap, Y. 2017. Synthesis of biodiesel from palm fatty acid distillate using sulfonated palm seed cake catalyst, Renewable Energy, 111, 611–619. https://doi.org/10.1016/j.renene.2017.04.056.

  3. Aladic, K., Jarni, K., Barbir, T., Vidovic, S., Vladic, J., Bilic, M., Jokic, S. 2015. Supercritical CO2 extraction of hemp (Cannabis sativa L.) seed oil. Industrial Crops and Products, 76, 472–478. https://doi.org/10.1016/j.indcrop.2015.07.016

  4. Atabani, A.E., Mahlia, T.M.I., Badruddin, I.A., Masjuki, H. H., Chong, W.T. 2013. Investigation of physical and chemical properties of potential edible and non-edible feedstocks for biodiesel production, a comparative analysis. Renewable and Sustainable Energy Reviews, 21, 749–755. https://doi.org/10.1016/j.rser.2013.01.027

  5. Barrales, F.M., Rezende, C.A., Martínez, J. 2015. Supercritical CO2 extraction of passion fruit (Passiflora edulis sp.) seed oil assisted by ultrasound. Journal of Supercritical Fluids, 104, 183–192. https://doi.org/10.1016/j.supflu.2015.06.006

  6. Celik, H., Gürü, M. 2015. Extraction of oil and silybin compounds from milk thistle seeds using supercritical carbon dioxide. Journal of Supercritical Fluids, 100, 105–109. https://doi.org/10.1016/j.supflu.2015.02.025

  7. Cheung, P. 1999. Temperature and pressure effects on supercritical carbon dioxide extraction of n-3 fatty acids from red seaweed. Food Chemistry, 65, 399–403. https://doi.org/10.1016/S0308-8146(98)00210-6

  8. Devi, B.L.A.P., Reddy, T.V.K., Lakshmi, K.V., Prasad, R.B.N. 2014. A green recyclable SO3H-carbon catalyst derived from glycerol for the production of biodiesel from FFA-containing karanja (Pongamia glabra) oil in a single step. Bioresource Technology, 153, 370–373. https://doi.org/10.1016/j.biortech.2013.12.002

  9. Friedrich, J.P., List, G.R. 1982. Characterization of soybean oil extracted by supercritical carbon dioxide and hexane. Journal of Agricultural and Food Chemistry, 30, 192–193. https://doi.org/10.1021/jf00109a044

  10. Gomez A.M., de la Ossa, E.M. 2002. Quality of borage seed oil extracted by liquid and supercritical carbon dioxide. Chemical Engineering Journal, 88, 103–109. https://doi.org/10.1016/S1385-8947(01)00260-1

  11. Goula, A. M. 2013. Ultrasound-assisted extraction of pomegranate seed oil – kinetic modeling. Journal of Food Engineering, 117, 492–498. https://doi.org/10.1016/j.jfoodeng.2012.10.009

  12. Guldi, D.M., Martin, N. 2010. “Carbon nanotubes and related structures: synthesis, characterization, functionalization and applications”. Wiley-VCH Verlag GmbH & Co. KGaA. Weinhein. USA.

  13. Istadi, I., Anggoro, D., Buchori, L., Rahmawati, D., Intaningrum, D. 2015. Active acid catalyst of sulphated zinc oxide for transesterification of soybean oil with methanol to biodiesel. Procedia Environmental Science, 23, 385–393. https://doi.org/10.1016/j.proenv.2015.01.055

  14. Kish, S.S., Rashid, A., Aghabozorg, H.R., Moradi, L. 2010. Increasing the octane number of gasoline using functionalized carbon nanotubes. Applied Surface Science, 256, 3472–3477. https://doi.org/10.1016/j.apsusc.2009.12.056

  15. Knothe, G., Razon, L., Bacani, F. 2013. Kenaf oil methyl esters. Industrial Crops and Products, 49, 568–572. https://doi.org/10.1016/j.indcrop.2013.06.003

  16. Knothe, G., de Castro, M., Razon, L. 2015. Methyl esters from and fatty acid profile of Gliricidia sepium seed oil. Journal of the American Oil Chemists’ Society, 92, 769–775. https://doi.org/10.1007/s11746-015-2634-3

  17. Larkeche, O., Zermane, A., Meniai, A.H., Crampon, C., Badens, E. 2015. Supercritical extraction of essential oil from Juniperus communis L. needles: Application of response surface methodology. Journal of Supercritical Fluids, 99, 8–14. https://doi.org/10.1016/j.supflu.2015.01.026

  18. Liu, G., Xu, X., Hao, Q., Gao, Y. 2009. Supercritical CO2 extraction optimization of pomegranate (Punica granatum L.) seed oil using response surface methodology. LWT- Food Science and Technology, 42, 1491–1495. https://doi.org/10.1016/j.lwt.2009.04.011

  19. Macawile, M.C.A., Quitain, A.T., Kida, T., Tan, R., J. Auresenia. 2020. “Green synthesis of sulfonated organosilane functionalized multiwalled carbon nanotubes and its catalytic activity for one-pot conversion of high free fatty acid seed oil to biodiesel,” Journal of Cleaner Production 275, 123–146. https://doi.org/10.1016/j.jclepro.2020.123146

  20. Melero, J.A., Bautista, L.F., Morales, G., Iglesias, J., Sánchez-Vázquez, R. 2010. Biodiesel production from crude palm oil using sulfonic acid-modified mesostructured catalysts. Chemical Engineering Journal, 161, 323–331. https://doi.org/10.1016/j.cej.2009.12.037

  21. Morales, G., Bautista, L.F., Melero, J.A., Iglesias, J., Sánchez-Vázquez, R. 2011. Low-grade oils and fats: Effect of several impurities on biodiesel production over sulfonic acid heterogeneous catalysts. Bioresource Technology, 102, 9571–9578. https://doi.org/10.1016/j.biortech.2011.07.082

  22. Pawliszyn, J. 2012. “Comprehensive sampling and sample preparation analytical techniques for scientists”. 1st ed., Academic Press.

  23. Porto, C.D., Decorti, D., Natolino, A. 2016. Microwave pretreatment of Moringa oleifera seed: Effect on oil obtained by pilot-scale supercritical carbon dioxide extraction and Soxhlet apparatus. Journal of Supercritical Fluids, 107, 38–43. https://doi.org/10.1016/j.supflu.2015.08.006

  24. Przygoda, K., Wejnerowska, G. 2015. Extraction of tocopherol-enriched oils from Quinoa seeds by supercritical fluid extraction. Industrial Crops and Products, 63, 41–47. https://doi.org/10.1016/j.indcrop.2014.09.038

  25. Rai, A., Mohanty, B., Bhargava, R. 2016. Supercritical extraction of sunflower oil: A central composite design for extraction variables. Food Chemistry, 192, 647–659. https://doi.org/10.1016/j.foodchem.2015.07.070

  26. Romano, S.D., Sorichetti, P.A. 2011. “Dielectric spectroscopy in biodiesel production and characterization, green energy and technology”. Springer-Verlag, London.

  27. Santos, P.D., Aguiar, A.C., Viganó, J., Boeing, J., Visentainer, J.V., Martínez, J. 2016. Supercritical CO2 extraction of cumbaru oil (Dipteryx alata Vogel) assisted by ultrasound: Global yield, kinetics and fatty acid composition. Journal of Supercritical Fluids, 107, 75–83. https://doi.org/10.1016/j.supflu.2015.08.018

  28. Shu, Q., Zhang, Q., Xu, G. Nawaz, Z., Wang, D., Wang, J. 2009. Synthesis of biodiesel from cottonseed oil and methanol using a carbon-based solid catalyst. Fuel Processing Technology, 90, 1002–1008. https://doi.org/10.1016/j.fuproc.2009.03.007

  29. Sodeifian, G., Sajadan, S.A., Ardestani, N.S. 2017. Supercritical fluid extraction of omega-3 from Dracocephalum kotschyi seed oil: Process optimization and oil properties. Journal of Supercritical Fluids, 119, 139–149. https://doi.org/10.1016/j.supflu.2016.08.019

  30. Suryaputra, W., Winata, I., Indraswati, N., Ismadji, S. 2013. Waste capiz (Amusium cristatum) shell as a new heterogeneous catalyst for biodiesel production. Renewable Energy, 50, 795–799. https://doi.org/10.1016/j.renene.2012.08.060

  31. US Department of Energy. 2004.Biodiesel: handling and uses guidelines, Energy Efficiency and Renewable Energy.

  32. Yu, H., Jin, Y., Li, Z., Peng, F., Wang, H. 2008. Synthesis and characterization of sulfonated single –walled carbon nanotubes and their performance as solid acid catalyst. Journal of Solid State Chemistry, 181, 432–438. https://doi.org/10.1016/j.jssc.2007.12.017


ARTICLE INFORMATION

Received: 2021-07-19
Revised: 2021-11-16
Accepted: 2021-11-22
Available Online: 2022-03-01


Cite this article:

Macawile, M.C., Joseph Auresenia. 2022. Comparison of biodiesel yield from seed oils extracted by ultrasound-assisted chemical solvent and supercritical CO2 methods. International Journal of Applied Science and Engineering, 19, 2021279. https://doi.org/10.6703/IJASE.202203_19(1).006

  Copyright The Author(s). This is an open access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are cited.

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