International Journal of Applied Science and Engineering
Published by Chaoyang University of Technology

Noor Fachrizal 1*, Hadi Surachman 1*, Titik Nurmawati 1Ahsonul Anam 2, Sutopo 1, Yosephine Merry Devina 3, Enny Rosmawar Purba 1

1Research Centre for Energy Conversion and Conservation, National Research and Innovation Agency, South Tangerang, Indonesia

2Research Center for Process and Manufacturing Industry Technology, National Research and Innovation Agency, South Tangerang, Indonesia

3Department of Chemical Engineering, University of Indonesia, Depok, Indonesia

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ABSTRACT


Agricultural wastes have huge biomass potency which can convert energy in the form of liquid fuel, solid, and syngas in one process by using the pyrolysis technique. The process can be driven to fast and flash pyrolysis to obtain yield in liquid form by using microwave heating method. This research started by developing an experimental laboratory apparatus by modifying a commercial microwave oven. It worked safely, and some experiments had been carried out. The process could run only 10–20 mins, much faster than conventional heating, which needs more than 2 hrs for pre-heating. By using chopped cashew nuts as raw material, bio-oil results were 9.33% and 25.00%. Dried algae and bagasse needed biochar as the material absorber. The experiments showed, dried algae with 0% and 10% biochar gained bio-oil yields of 3.19% and 15.00%. Feeding bagasse as raw materials with 0%, 10%, and 20% biochar, resulted in bio-oil of 42.45%, 39.10%, and 42.75%. GC/MS analysis of bio-oil identified that it contained 42.24% of non-oxygenatic compounds and 57.76% of oxygenatic compounds. This non-oxygenatic compound contains a long and stable carbon chain. These results proved that the experimental apparatus can work properly and safely.


Keywords: Biomass, Fast pyrolysis, Microwave, Bio-oil.


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REFERENCES


  1. Aboelela, D., Saleh, H., Attia, A.M., Elhenawy, Y., Majozi, T., Bassyouni, M. 2023. Recent advances in biomass pyrolysis processes for bioenergy production: optimization of operating conditions. Sustainability, 15, 11238.

  2. Ábrego, J., Plaza, D., Luño, F., Atienza-Martínez, M., Gea, G. 2018. Pyrolysis of cashew nutshells: Characterization of products and energy balance. Energy, 158, 72–80.

  3. Adekanbi, M.L., and Olugasa, T.T. 2022. Utilizing cashew nut shell liquid for the sustainable production of biodiesel: A comprehensive review. Cleaner Chemical Engineering, 4, 100085.

  4. Akhtar, J., and Amin, N.S. 2012. A review on operating parameters for optimum liquid oil yield in biomass pyrolysis. Renewable and Sustainable Energy Reviews, 16, 5101–5109.

  5. Al-Mashhadani, N.H., Khudhair, M.M., Mohamed, A.A., Al Kareem, Z.A., Ali, E.M., Mohsun, E.A.AL, Mahmood, A.S., Jaseem, M.M. 2014. Improvement of gasoline octane number by using organic compounds. Baghdad Science Journal, 11, 502–508.

  6. Amaliyah, N. and Putra, A.E.E. 2021. Microwave-assisted pyrolysis of cashew nut shell. International Journal of Design and Nature and Ecodynamics, 16(2), 227–232.

  7. Bridgwater, A.V. 2012. Review of fast pyrolysis of biomass and product upgrading. Biomass and Bioenergy, 38, 68–94.

  8. Bridgwater, A.V., Meier, D., Radlein, D. 1999. An overview of fast pyrolysis of biomass. Organic Geochemistry, 30, 1479–1493.

  9. Castro, D.A.R., Ribeiro, H.J.S., De Guerreiro, L.H.H., Bernar, L.P., Bremer, S.J., Santo, M.C., Almeida, H.D., Duvoisin jr.,S., Borges, L.E.P., Machado, N.T. 2021. Production of fuel-like fractions by fractional distillation of bio-Oil from Açaí (Euterpe oleracea Mart.) seeds pyrolysis. Energies, 14, 3713.

  10. Czarnocka, J. 2015. The use of microwave pyrolysis for biomass processing. Archiwum Motoryzacji, 67(1), 11–21.

  11. De Sousa Leite, K., de Carvalho, A.A.Jr, Teixeira, P.R.S., de Matos, J.M.E., 2023. Cashew nut shell liquid as an anticorrosive agent in ceramic materials. Sustainability, 15, 8743.

  12. Diaz, F., Wang, Y., Moorthy, T., Friedrich, B. 2018. Degradation mechanism of nickel-cobalt-aluminum (NCA) cathode material from spent lithium-ion batteries in microwave-assisted pyrolysis. Metals, 8, 565.

  13. Du, Z., Li, Y., Wang, X., Wan, Y., Chen, Q., Wang, C., Lin, X., Liu, Y., Chen, P., Ruan, R. 2011. Microwave-assisted pyrolysis of microalgae for biofuel production. Bioresource Technology, 102, 4890–4896.

  14. Ethaib, S., Omar, E., Kamal, S.M.M., Biak, D.R.A., Zubaidi,S.L. 2020. Microwave_assisted pyrolysis of biomass waste : a mini review. Processes, 8, 1190.

  15. Fachrizal, N., Heruhadi, B., Mustafa, R., Sumarsono, M., Pranoto, S. 2008. Pembuatan arang briket ampas jarak dan biomassa. Jumal IImiah Teknolgi Energi, 98524.

  16. Fernandez, Y., Arenillas, A., Angel, J. 2011. Microwave heating applied to pyrolysis. Advances in induction and microwave heating of mineral and organic materials. Intech.

  17. Giorcelli, M., Das, O., Sas, G., Försth, M., Bartoli, M. 2021. A review of bio-oil production through microwave- assisted pyrolysis. Processes, 9, 1–17.

  18. Heyerdahl, P., Gilpin, G., Ruan, R., Chen, P., Yu, F., Hennessy, K., Wang, Y., Wu, J., Tunheim, A. 2012. Distributed biomass conversion. Oslo: Norwegian University.

  19. Hidayati, N., and Ekayuliana, A. 2022. Studi potensial energi biomassa dari limbah pertanian dan perkebunan di Indonesia. Seminar Nasional Inovasi Vokasi, 1, 130–135.

  20. Huang, Y.F., Chiueh, P. Te, Lo, S.L. 2016. A review on microwave pyrolysis of lignocellulosic biomass. Sustainable Environment Research, 26, 103–109.

  21. Jahirul, M.I., Rasul, M.G., Chowdhury, A.A., Ashwath, N. 2012. Biofuels production through biomass pyrolysis- A technological review. Energies, 5, 4952–5001.

  22. Kang, S.B., Kim, J.J., Im, Y.H. 2013. An experimental investigation of a direct burning of crude Jatropha oil (CJO) and pitch in a commercial boiler system. Renewable Energy, 54, 8–12.

  23. Kawahara, Y., Bian, X., Shigeta, R., Vyas, R., Tentzeris, M.M., Asami, T. 2013. Power harvesting from microwave oven electromagnetic leakage. Proceedings of the 2013 ACM International Joint Conference on Pervasive and Ubiquitous Computing: pp. 373-382. http://dx.doi.org/10.1145/2493432.2493500..

  24. Kong, X,, Gong, Y., Mao, S., Yong, W., 2018. Selective hydrogenation of phenol. ChemNanoMat, 4, 1–20.

  25. Lin, B.J., and Chen, W.H. 2015. Sugarcane bagasse pyrolysis in a carbon dioxide atmosphere with conventional and microwave-assisted heating. Frontiers in Energy Research, 3, 1–9.

  26. Lin, F., Waters, C.L., Mallinson, R.G., Lobban, L.L., Bartley, L.E. 2015. Relationships between biomass composition and liquid products formed via pyrolysis. Frontiers in Energy Research, 3, 45.

  27. Mahmud, M.A., and Anannya, F.R. 2021. Sugarcane bagasse - A source of cellulosic fiber for diverse applications. Heliyon, 7, e07771.

  28. Martins, A.A., Marques, F., Cameira, M., Santos, E., Badenes, S., Costa, L., Vieira, V.V., Caetano, N.S., Mata, T.M. 2018. Water footprint of microalgae cultivation in photobioreactor. Energy Procedia, 153, 426–431.

  29. Metaxas, A.C. 1991. Microwave heating. IEEE Power Engineering Journal, 5, 237–247.

  30. Miranda, N.T., Motta, I.L., Filho, R.M., Regina, M., Maciel, W. 2021. Sugarcane bagasse pyrolysis : A review of operating conditions and products properties. Renewableand Sustainable Energy Reviews, 149, 111394.

  31. Mohabeer, C., Guilhaume, N., Laurenti, D., Schuurman, Y. 2022. Microwave-assisted pyrolysis of biomass with and without use of catalyst in a fluidised bed reactor: A Review. Energies, 15, 3258.

  32. Motasemi, F., Salema, A.A., Afzal, M.T. 2015. Microwave dielectric properties of agricultural biomass at high temperature and in inert environment. Transactions of the ASABE, 58, 869–877.

  33. Novita, S.A., Santosa., Nofialdi., Andasuryani., Fudholi A., Putera, P. 2022. Fast pyrolysis of biomass with concentrated solar power : A Review. Journal of Applied Agricultural Science and technology, 6, 180–191.

  34. Onay, O. 2007. Influence of pyrolysis temperature and heating rate on the production of bio-oil and char from safflower seed by pyrolysis, using a well-swept fixed-bed reactor. Fuel Processing Technology, 88, 523–531.

  35. Panwar, N.L. and Paul, A.S. 2021. An overview of recent development in bio-oil upgrading and separation techniques. Environmental Engineering Research, 26, 200382.

  36. Patel, A., Agrawal, B., Rawal, B.R. 2020. Pyrolysis of biomass for efficient extraction of biofuel. Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 42, 1649–1661.

  37. Pawar, A., Panwar, N.L., Salvi, B.L. 2020. Comprehensive review on pyrolytic oil production , upgrading and its utilization. Journal of Material Cycles and Waste Management, 22, 1712–1722.

  38. Pidtasang, B., Udomsap, P., Sukkasi, S., Chollacoop, N., Pattiya, A. 2013. Influence of alcohol addition on properties of bio-oil produced from fast pyrolysis of eucalyptus bark in a free-fall reactor. Journal of Industrial and Engineering Chemistry, 19, 1851–1857.

  39. Pratiwi, I.A.P., Saptoadi, H., Santanuhady, J., Purnomo, C.W., Rohmat, T.A. 2022. Tetrapak waste treatment using microwave pyrolysis to produce alternative gas fuels. International Journal of Applied Science and Engineering, 19, 2022078.

  40. Raza, M., Inayat, A., Ahmed, A., Jamil, F., Ghenai, C., Naqvi, S.R., Shanableh, A., Ayoub, M., Waris, A., Park, Y. K. 2021. Progress of the pyrolyzer reactors and advanced technologies for biomass pyrolysis processing. Sustainability, 13, 1–42.

  41. Robinson, J., Dodds, C., Stavrinides, A., Kingman, S., Katrib, J., Wu, Z., Medrano, J., Overend, R. 2015. Microwave pyrolysis of biomass: Control of process parameters for high pyrolysis oil yields and enhanced oil quality. Energy and Fuels, 29, 1701–1709.

  42. Sadaka, S., Sharara, M.A., Ashworth, A., Keyser, P., Allen, F., Wright, A. 2014. Characterization of biochar from switchgrass carbonization. Energies, 7, 548–567.

  43. Saenab, A., Wiryawan, K.G., Yuli, R., Wina, E., 2016. Karakteristik fisik dan kimia dari produk bioindustri cangkang cashewnuts shell (Anacardium Occidentale), Jurnal Littri 22, 81–90.

  44. Salema, A.A., and Ani, F.N. 2010. Microwave pyrolysis ofoil palm fibres. Jurnal Mekanikal, Universiti Teknologi Malaysia, 30, 77–86

  45. Solar, J., de Marco, I., Caballero, B.M., Lopez-Urionabarrenechea, A., Rodriguez, N., Agirre, I., Adrados, A. 2016. Influence of temperature and residence time in the pyrolysis of woody biomass waste in a continuous screw reactor. Biomass and Bioenergy, 95, 416–423.

  46. Stroescu, M., Marc, R.A., Muresan, C.C., 2024. A comprehensive review on sugarcane bagasse in food packaging: Properties, applications, and future prospects. Hop and Medicinal Plants, 32, 169–184.

  47. Terry, L.M., Li, C., Chew, J.J., Aqhsa, A., Bing, S.H., Chun, M.L.A., Lai, F.C.B., Khaerudini, D.S., Hameedm N., Guoqing, G., Sunarso, J. 2021. Bio-oil production from pyrolysis of oil palm biomass and the upgrading technologies: A review. Carbon Resources Conversion, 4, 239–250.

  48. Tripathi, M., Sahu, J.N., Ganesan, P. 2016. Effect of process parameters on production of biochar from biomass waste through pyrolysis : A reveiew. Renewable and Sustainable Energy Reviews, 55, 467–481.

  49. Vamvuka, D., Esser, K., Marinakis, D. 2023. Characterization of Pyrolysis Products of Forest Residues and Refuse-Derived Fuel and Evaluation of Their Suitability as Bioenergy Sources. Appl. Sci. 13, 1482. https://doi.org/10.3390/app13031482

  50. Wang, S., Guo, Z., Cai, Q., Guo, L. 2012. Catalytic conversion of carboxylic acids in bio-oil for liquid hydrocarbons production. Biomass and Bioenergy, 45, 138–143.

  51. Waters, C.L., Janupala, R.R., Mallinson, R.G., Lobban, L.L. 2017. Staged thermal fractionation for segregation of lignin and cellulose pyrolysis products: An experimental study of residence time and temperature effects. Journal of Analytical and Applied Pyrolysis, 126, 380–389.

  52. Xia, S., Wang, C., Chen, Y., Kang, S., Zhao, K., Zheng, A., Zhao, Z., Li, H. 2022. Sustainable aromatic production from catalytic fast pyrolysis of 2-methylfuran over metal-modified ZSM-5. Catalysts, 12, 1–10.

  53. Yang, H., Yan, R., Chen, H., Lee, D.H., Zheng, C. 2007. Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel, 86, 1781–1788.

  54. Yi, W., Bai, X., He, F., Li, Z., Li, Y., Wanglihong, Xiu, S. 2005. Bio-oil from agricultural residues by fast pyrolysis. In 2005 ASAE Annual Meeting. American Society of Agricultural and Biological Engineers.

  55. Zhang, Y., Chen, P., Liu, S., Fan, L., Zhou, N., Min, M., Cheng, Y., Peng, P., Anderson, E., Wang, Y., Wan, Y., Liu, Y., Li, B., Ruan, R. 2017. Microwave-assisted pyrolysis of biomass for bio-oil production. Pyrolysis, 129–166.


ARTICLE INFORMATION


Received: 2024-02-14
Revised: 2025-03-20
Accepted: 2025-04-17
Available Online: 2025-05-15


Cite this article:

Fachrizal N., Surachman H., Nurmawati T., Anam A., Sutopo , Devina Y.M., Purba E.R. 2025. Development of microwave-assisted pyrolysis apparatus and some experiments on agricultural biomass wastes: cashew shells, bagasse, and dried algae. International Journal of Applied Science and Engineering, 22, 2025039.https://doi.org/10.6703/IJASE.202506_22(2).001

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